Carbon capture plants deploy several methods ranging from membranes, to amine-based technologies that involve components which degrade into ammonia, formamide, aldehydes, organic acids, nitrosamines and other toxic gaseous species. Gas products pose challenges for sampling and analysis given the presence of water vapor and high concentrations of carbon dioxide as well as certain water-soluble compounds.

There are currently stationary and semi-portable hot-wet FTIR (Fourier Transform Infrared Spectroscopy) instruments for online analysis and gas emissions monitoring from such plants. These units scan a wide wavenumber spectrum where several species absorb infrared light, allowing to simultaneously measure more than 25 gases. FTIR analytes include standard criteria pollutants such as CH4, CO2, NOx, SO2, acid gases, NH3, aldehydes, and other VOCs, and extend to amines and amine by-products observed in CO2 absorber and amine stripping towers. Some of these substances are ecotoxic, have low biodegradability, and are known to cause cancer.

This presentation reviews FTIR principles, sampling solutions, and available configurations for online gas analysis at carbon capture and storage plants. It highlights industrial and laboratory scale case studies using semi-portable and CEM systems, and advantages as related to analytical performance, component flexibility, and maintenance requirements.

Co-Author:  Jim Cornish, Gasmet Technologies

QUESTIONS

1. How are different gas matrices and concentrations analyzed?
2. What gas components cannot be monitored with FTIR?
3. Can I measure from multiple sampling points within a plant?